| Cao Cao |
Clear Musou Mode with 3 Wei characters |
| Cao Pi |
Deafeat Cao Pi within 5 minutes on Wu side of He Fei |
| Diao Chan |
Clear Musou Mode with 1 character from each Kingdom |
| Dong Zhuo |
Clear Musou Mode with Lu Bu |
| Gan Ning |
Clear Musou Mode with 1 Wu character |
| Guan Ping |
Succeed in 2 battle objectives on the Shu side of Fan Castle and finish battle with Guan Ping alive |
| Huang Zhong |
Succeed in 1 battle objective on the Wei side of Ding Jun Mountain |
| Liu Bei |
Clear Musou Mode with 3 Shu characters |
| Lu Bu |
Clear Musou Mode with Liu Bei, Cao Cao, and Sun Jian |
| Lu Meng |
Succeed in 2 battle objectives on the Wei side of He Fei |
| Ma Chao |
Succeed in 2 battle objectives on the Wei side of Han Zhong Attack Defense Battle |
| Pang Tong |
Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive |
| Sun Jian |
Clear Musou Mode with 3 Wu characters |
| Wei Yan |
Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive |
| Xiahou Yuan |
Succeed in 1 battle objective on the Shu side of Ding Jun Mountain |
| Xu Huang |
Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle |
| Zhang Liao |
Clear Musou Mode with 1 Wei character |
| Zheng He |
Succeed in 2 battle objectives on the Shu side of Han Zhong Attack Defense Battle |
| Zhou Tai |
Succeed in 3 battle objectives on the Shu side of Yi Ling |
| Zhuge Liang |
Clear Musou Mode with 1 Shu character |